Resonance Raman spectroscopy of FeII FeIII and FeIII FeIII model complexes containing an unsymmetrical dinucleating ligand: a biomimetic redox pair for uteroferrin
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چکیده
منابع مشابه
Resonance Raman Spectroscopy of FeIIFeIII and FeIIIFeIII Model Complexes Containing an Unsymmetrical Dinucleating Ligand: A Biomimetic Redox Pair for Uteroferrin
Neste trabalho, investigamos os perfis de excitação Raman do complexo [FeFe(bpbpmp) (C 2 H 3 O 2 ) 2 ](ClO 4 ) (1) e de sua inédita forma oxidada, [FeFe(bpbpmp)(C 2 H 3 O 2 ) 2 ](ClO 4 ) 2 (2), sendo bpbpmp a molécula 2-bis[{(2-piridilmetil)-aminometil}-6-{(2-hidroxibenzil)(2piridilmetil)}-aminometil]-4-metilfenol. No complexo 1, o modo vibracional mais intensificado no espectro Raman é o corre...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2006
ISSN: 0103-5053
DOI: 10.1590/s0103-50532006000800025